Growth of uniform lath-like α-(Fe,Al)OOH and disc-like α-(Fe,Al)2O3 nanoparticles in a highly alkaline medium

The effects of aluminium (Al3+)-dopant on the precipitation of uniform lath-like α-FeOOH particles, the obtention and growth of α-(Fe,Al)OOH and α-(Fe,Al)2O3 solid solutions, particle size and shape were investigated using X-ray powder diffraction, Mössbauer and Fourier transform infrared spectroscopies, field emission scanning electron microscopy and energy dispersive X-ray spectroscopy. Acicular α-FeOOH particles, precipitated in a highly alkaline medium with the addition of tetramethylammonium hydroxide (TMAH), were used as reference material. The influence of Al-dopant was investigated by adding varying amounts of Al3+ ions to the initial FeCl3 solution. In the presence of lower concentrations of aluminium ions (up to 11.11 mol%) α-(Fe,Al)OOH as a single phase was formed, whereas higher concentrations led to an additional obtention and growth of α-(Fe,Al)2O3. Al-for-Fe substitution in the α-FeOOH and α-Fe2O3 structures was confirmed by a decrease in the unit-cell dimensions, a decrease in the hyperfine magnetic field and an increase in the wave number of the infrared absorption bands. The presence of lower concentrations of aluminium ions (up to 11.11 mol%) in the precipitation system did not affect the size and shape of the α-(Fe,Al)OOH particles, whereas higher concentrations influenced a decrease in the length and aspect ratio. In the presence of 42.86 mol% Al3+ ions fairly uniform disc-shaped α-(Fe,Al)2O3 were formed.