Early stages of oxidation of Ti3AlC2 ceramics

The nucleation and growth of oxide scale at the early stages of oxidation of Ti3AlC2 ceramics was studied via oxidizing at 1100 °C in air for short times (≤900 s). The nucleation of nanosized Al2O3 particles mainly occurs at the ledges of the fractured lamellar Ti3AlC2 grains as well as on the {0 0 0 1} basal surfaces. The Al2O3 nuclei mainly grow along these ledges to form oxide strings, and then spread on the terraces and the {0 0 0 1} basal surfaces. An oxide layer consisting predominantly of nanosized α-Al2O3 forms after oxidizing for 180 s. The formation of lenticular hexagonal pores in Ti3AlC2 grains is attributed to the faster consumption of Ti, Al and C atoms along 〈1 1 2¯ 0〉 direction than along 〈0 0 0 1〉 direction. With further oxidation, rutile-TiO2 particles form on top of the α-Al2O3 layer, and grow to form a rutile-TiO2 layer. Further oxidation leads to the formation of pores underneath the primary α-Al2O3 layer. In this porous layer both Al2O3 and TiO2 were present with a preference for Al2O3 to stay adjacent to the inward moving interface of Ti3AlC2 substrate.