Preparation, characterization and properties of acid functionalized multi-walled carbon nanotube reinforced thermoplastic polyurethane nanocomposites

The multi-walled carbon nanotube (MWNT) reinforced thermoplastic polyurethane (TPU) nanocomposites were prepared through melt compounding method followed by compression molding. The spectroscopic study indicated that a strong interfacial interaction was developed between carbon nanotube (CNT) and the TPU matrix in the nanocomposites. The microscopic observation showed that the CNTs were homogeneously dispersed throughout the TPU matrix well apart from a few clusters. The results from thermal analysis indicated that the glass transition temperature (Tg) and storage modulus (E′) of the nanocomposites were increased with increase in CNTs content and their thermal stability were also improved in comparison with pure TPU matrix. The rheological analysis showed the low frequency plateau of shear modulus and the shear thinning behavior of the nanocomposites. The electrical behaviors of the nanocomposites are increased with increase in weight percent (wt%) of CNT loading. The mechanical properties of nanocomposites were substantially improved by the incorporation of CNTs into the TPU matrix.

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► Preparation and characterization of TPU nanocomposite for tailor made applications.
► The structural analyses were carried out by FTIR, WAXD, FESEM and HRTEM.
► The thermal and dynamic mechanical properties were evaluated by TGA, DSC and DMA.
► The dynamic rheological behavior was investigated by RPA in frequency sweep.
► The frequency dependence of electrical properties was studied by LCR meter.