کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1530414 1511993 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of novel aromatic-aliphatic polyamides from bis-[(4-aminobenzyl)-4-benzamide] ether
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of novel aromatic-aliphatic polyamides from bis-[(4-aminobenzyl)-4-benzamide] ether
چکیده انگلیسی
A novel aromatic diamine monomer containing preformed aromatic-aliphatic amide and ether linkage, bis-[(4-aminobenzyl)-4-benzamide] ether (BABE) was prepared from 2-phenylacetonitrile. BABE was characterized by FT-IR, 1H NMR, 13C NMR and mass spectrometry. Five new aromatic polyamides were prepared by low temperature solution polymerization from BABE and different mole proportions of isophthaloyl chloride (IPC) or terephthaloyl chloride (TPC). The resulting polymers were characterized by means of FT-IR, inherent viscosity [ηinh], solubility, differential scanning calorimetry [DSC], thermogravimetric analysis [TGA] and X-ray diffraction [XRD]. Polyamides were obtained in good yields and had moderate to high molecular weights as indicated by inherent viscosities in the range 0.63-1.35 dL/g in (DMAc + 4% LiCl). XRD results showed the partly crystalline nature of polymers and these polymers dissolved in aprotic polar solvents containing LiCl. The solubility of copolyamides improved due to random placement of constituent IPC and TPC during polymerization. DSC analysis of these polyamides showed glass transition temperatures in the range of 197-204 °C, and they showed no weight loss below 336 °C when analyzed by TG. These polyamides have potential applications as engineering materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science and Engineering: B - Volume 168, Issues 1–3, 15 April 2010, Pages 111-116
نویسندگان
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