کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1552250 998181 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study on surface states of Pt/TiO2 thin film in different atmospheres
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
پیش نمایش صفحه اول مقاله
Study on surface states of Pt/TiO2 thin film in different atmospheres
چکیده انگلیسی

In this paper, the surface states of Pt/TiO2 thin film were tested in air, H2 and N2 flows. Pt/TiO2 was prepared by means of photoreduction of PtCl62- on anatase nano-TiO2 powders and was coated on the microscopy glass using powder–sol technique. Powder conductivity method was applied in the analysis of surface states. The experimental results show that a new surface state was formed in air flow; which was 0.43 eV lower than the conduction band edge of TiO2. In N2 flow, three surface states, with the energy levels of 0.42, 0.62 and 0.90 eV, respectively, were detected. Compared with that tested in airflow, 0.42 and 0.62 eV could be attributed to Pt and floating bond of TiO2 respectively, while 0.90 eV might have resulted from the Ti3+ formed at high temperature in N2 flow. The conductivity of the sample tested in H2 flow increased significantly and was almost unchanged with temperature, which could be interpreted by the dissociative adsorption of H2 on Pt.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solar Energy - Volume 81, Issue 10, October 2007, Pages 1280–1284
نویسندگان
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