کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1556163 | 1513713 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxygen Permeation and Stability of Ce0.8Gd0.2O2âδ-PrBaCo2âxFexO5+δ Dual-phase Composite Membranes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
شیمی مواد
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Oxygen Permeation and Stability of Ce0.8Gd0.2O2âδ-PrBaCo2âxFexO5+δ Dual-phase Composite Membranes Oxygen Permeation and Stability of Ce0.8Gd0.2O2âδ-PrBaCo2âxFexO5+δ Dual-phase Composite Membranes](/preview/png/1556163.png)
چکیده انگلیسی
Dual-phase membranes of 60 wt% Ce0.8Gd0.2O2âδ-40 wt% PrBaCo2-xFexO3âδ (0 â¤Â x â¤Â 2) were prepared by a combined citrate and ethylene diamine tetraacetic acid (EDTA) complexing method. X-ray diffraction (XRD) results revealed the good chemical compatibility between ion-conducting phase CGO and electron-conducting phases PBC2âxFxO after sintering in air. The Fe ionic dopant had a significant effect on the phase structure stability and oxygen permeability under CO2 atmosphere, which was confirmed by XRD, thermogravimetry-differential scanning calorimetry (TG-DSC), scanning electron microscopy (SEM) and oxygen permeation experiments. CGO-PBC0.5F1.5O dual-phase membrane demonstrated a stable oxygen permeation flux of 2.71 Ã 10â7 mol cmâ2 sâ1 with 50 mol% He/CO2 as the sweep gas at 925 °C, and this value was much higher than that of perovskite-type membranes. The rate-limiting step in the oxygen permeation process changed from the bulk diffusion to the surface oxygen exchange when the CGO-PBC0.5F1.5O membrane thickness decreased to 0.8 mm or less. Due to the high oxygen permeation fluxes and the excellent structural stability under CO2 atmosphere, the CGO-PBC0.5F1.5O membrane is a great potential candidate material for separating oxygen from air in the oxy-fuel combustion techniques.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Materials Science & Technology - Volume 30, Issue 12, December 2014, Pages 1174-1180
Journal: Journal of Materials Science & Technology - Volume 30, Issue 12, December 2014, Pages 1174-1180
نویسندگان
Bo Jiang, Hongwei Cheng, Longfei Luo, Xionggang Lu, Zhongfu Zhou,