کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1556566 | 999197 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Room Temperature Ferromagnetism in Dual Doped (Mn2+, Ni2+) ZnO Codoped with Li1+ Prepared Using EDTA Sintered at Low Temperature
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
شیمی مواد
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![عکس صفحه اول مقاله: Room Temperature Ferromagnetism in Dual Doped (Mn2+, Ni2+) ZnO Codoped with Li1+ Prepared Using EDTA Sintered at Low Temperature Room Temperature Ferromagnetism in Dual Doped (Mn2+, Ni2+) ZnO Codoped with Li1+ Prepared Using EDTA Sintered at Low Temperature](/preview/png/1556566.png)
چکیده انگلیسی
Nanopowders of Zn1âxâyâzMnxNiyLizO [(x = 0.04, y = 0, z = 0), (x = 0.04, y = 0.03, z = 0) and (x = 0.04, y = 0.03, z = 0.03)] have been synthesized by sol-gel precursor route using ethylene diamine tetraacetic acid (EDTA) as a metal chelating agent. X-ray diffraction analysis confirms the formation of wurtzite hexagonal structure for all the three compositions. Mn2+ doped ZnO exhibits room temperature ferromagnetism (RTFM), and it is found that further Ni2+ doping has decreased Ms because of limit of solid solubility of transition metal in ZnO. But codoping of monovalent Li1+, further increases the ferromagnetism (FM) value, due to introduction of free carriers compared to the dual doped samples. Photoluminescence (PL) spectra of the system, exhibit near band edge (NBE) emission peak at â¼464 nm due to the electron transition from interstitials to the valence band. Recombination of conduction electron with hole trapped at oxygen vacancy, leads to prominent defect emission peaks at â¼482 nm and 532 nm. The evidence of the formation of metal-EDTA complexes are found from the Fourier transform infrared spectra at 2800-3800 cmâ1 with shifting, splitting of the peak and also drastic variations in the intensity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Materials Science & Technology - Volume 30, Issue 3, March 2014, Pages 275-279
Journal: Journal of Materials Science & Technology - Volume 30, Issue 3, March 2014, Pages 275-279
نویسندگان
R. Pugaze, A. Sivagamasundari, D. Vanidha, S. Chandrasekar, A. Arunkumar, S. Rajagopan, R. Kannan,