Graphene/Si multilayer structure anodes for advanced half and full lithium-ion cells

► A rationally designed graphene/Si multilayer nanostructures for use as binder-free anodes in rechargeable LIBs. ► Novel strategy to incorporate dissimilar functional materials into one entity. ► Improved electrochemical performance demonstrated for both half and full cells. ► Scalable fabrication methods. ► Abundant, low-cost, non-toxic materials.