کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1558617 | 999316 | 2007 | 5 صفحه PDF | دانلود رایگان |
The growth mechanism of carbon nano-materials by arc discharge in water or liquid nitrogen was investigated using a special arc discharge apparatus. High-resolution transmission electron microscopy was used to observe and analyze the products. Results indicated that multi-walled carbon nanotubes (MWCNTs) and carbon onions can be produced by arc discharge in water and liquid nitrogen respectively. Single-walled carbon nanohorns can be produced by arc discharge in liquid nitrogen, and cobalt encapsulated carbon nano-particles can be produced by cobalt catalyzed carbon arc discharge in water. The liquids acted as quenching walls for the nucleation and growth of carbon nano-materials, resulting in the formation of different forms of carbon nano-materials. A cross alternating magnetic field with a frequency 5 Hz can affect the nucleation of nano-materials to form MWCNTs or carbon onions because nucleation time is longer than the periodicity of the magnetic field. Based on the experimental phenomena, a primary physical model was proposed to interpret the growth of nano-materials by arc discharge in liquids.
Journal: New Carbon Materials - Volume 22, Issue 4, December 2007, Pages 337-341