کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1559055 | 999341 | 2011 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Measurement of oxygen potential of (U0.8Pu0.2)O2±x at 1773 and 1873 K, and its analysis based on point defect chemistry
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Oxygen potential, G¯O2, of (U0.8Pu0.2) O2±x was measured at 1773 and 1873 K by a gas equilibrium method using a thermogravimeter. The measurement data were analyzed based on point defect chemistry, and the partial Gibbs energies at stoichiometric composition were determined from the analysis results which were obtained by using the relationship between deviation of stoichiometric composition x and oxygen partial pressure PO2, xâPO2±1/2, in the near stoichiometric region. The G¯O2 was represented as functions of the deviation x and temperature, being the calculation results in good agreement with experimental data. The G¯O2 at stoichiometric composition was described by the equation: G¯O2(J/mol)=â517.5Ã103+116.5â
T.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Calphad - Volume 35, Issue 4, December 2011, Pages 623-626
Journal: Calphad - Volume 35, Issue 4, December 2011, Pages 623-626
نویسندگان
Masato Kato, Shinya Nakamichi, Kentaro Takeuchi, Takeo Sunaoshi,