کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1559114 999344 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic modeling of the Mg–Si system with the Kaptay equation for the excess Gibbs energy of the liquid phase
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
Thermodynamic modeling of the Mg–Si system with the Kaptay equation for the excess Gibbs energy of the liquid phase
چکیده انگلیسی

The Mg–Si system was re-modeled using the Kaptay equation Li=hi⋅exp(−T/ti)(i=0,1,2,…) to describe the excess Gibbs energy of the liquid phase. Compared with the previous assessments using a linear temperature dependence: Li=ai+bi⋅T(i=0,1,2,…) to describe this excess Gibbs energy, the artificial inverted miscibility gap at high temperature is removed. In order to clarify the discrepancies among the literature data concerning the enthalpy of formation for Mg2Si, a first-principles calculation was performed to compute this thermodynamic quantity. The calculated phase diagram and thermodynamic properties using the obtained thermodynamic parameters agree well with the experimental data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Calphad - Volume 33, Issue 4, December 2009, Pages 673–678
نویسندگان
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