کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1571703 1000650 2011 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural studies of SrFeO3 and SrFe0.5Nb0.5O3 by employing XRD and XANES spectroscopic techniques
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
Structural studies of SrFeO3 and SrFe0.5Nb0.5O3 by employing XRD and XANES spectroscopic techniques
چکیده انگلیسی

The perovskite based SrFeO3 and SrFe0.5Nb0.5O3 materials have been synthesized by solid state reaction methods. The structural properties are investigated using a combination of X-ray diffraction and X-ray absorption fine structure spectroscopic techniques. From the Rietveld refinement of the X-ray diffraction data it has been observed that SrFeO3 has a simple cubic perovskite structure, which is consistent with the previous literature results; whereas SrFe0.5Nb0.5O3 shows a tetragonal structure within P4mm space group. X-ray absorption results demonstrate that the valence state of Fe in SrFeO3 is (IV); however, it changes to (III) when 50% Nb5+ is substituted at the Fe sites.


► Structural studies by employing XRD and XANES spectroscopic techniques.
► Rietveld refinement confirmed SrFeO3 has cubic structure, space group Pm-3m.
► It is revealed that SrFe0.5Nb0.5O3 has tetragonal structure, in P4mm space group.
► From XANES results it is observed that Fe has valence state of (IV) in SrFeO3.
► Doping of 50% Nb5+ at Fe sites, changes Fe valence to (III) in SrFe0.5Nb0.5O3.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Characterization - Volume 62, Issue 10, October 2011, Pages 1016–1020
نویسندگان
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