Precipitation behavior of grain boundary M23C6 and its effect on tensile properties of Ni–Cr–W based superalloy

Precipitation behavior of grain boundary (GB) M23C6 and its effect on tensile properties at elevated temperature were investigated systematically in a Ni–Cr–W based superalloy. The results show that the M23C6 precipitation behavior is influenced obviously by grain boundary character (GBC) and interfacial energy. The Σ≤9 GBs and low angle GBs have low interfacial energy, and no M23C6 carbide precipitates at these GBs. Plenty of M23C6 carbide particles precipitate at the large angle GBs with high interfacial energy. The coherent orientation relationship between M23C6 and the matrix plays an important role on the precipitation morphology of M23C6. M23C6 carbides with four typical morphologies distribute at the large angle GBs, including lamellar carbide which grows into the matrix near one side or both sides of the GBs, rod-like carbide and small lamellar carbide both of which grow along GBs. Moreover, the decrease of both tensile and yield strength of the aged alloy is mainly caused by the lamellar M23C6 carbide breaking. The tensile properties vary irregularly with increasing aging time.

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► M23C6 precipitation can be inhibited by the Σ≤9 GBs and low angle GBs in Ni–Cr–W based superalloy.
► M23C6 carbides with four typical morphologies precipitate at the large angle GBs.
► The coherent orientation relationship between M23C6 and the matrix plays an important role on the precipitation morphology of M23C6.
► The decreasing strength of aged alloy can mainly be caused by lamellar M23C6 carbide breaking.