کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1580063 1645418 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Investigation of hydrogen storage in carbon nanotube–magnesium matrix composites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
Investigation of hydrogen storage in carbon nanotube–magnesium matrix composites
چکیده انگلیسی

Magnesium (Mg) and magnesium nickel (Mg–23.5 wt%Ni) reinforced with multiwalled carbon nanotubes (CNTs) were processed by powder metallurgy and then charged with hydrogen by annealing at 620 K under a pressure of 0.4 MPa of hydrogen. Mechanical spectroscopy revealed that such a treatment has no effect in the composites with pure Mg matrix. On the other hand, Mg–23.5 wt%Ni alloys, unreinforced as well as reinforced with CNTs, exhibit a mechanical loss spectrum, which is deeply modified by hydrogen charging. Two relaxation peaks are observed at ∼190 K and ∼330 K (frequency ∼6 kHz), the height of which increases strongly with hydrogen charging. These peaks may be interpreted by atomic relaxation due to hydrogen in the Mg2Ni phase. Both peaks decrease strongly in height by degassing under vacuum at 750 K. In bulk specimens of Mg–23.5 wt%Ni/CNTs composites a concentration of hydrogen as high as 6.1 wt% (∼86% of specific weight of liquid hydrogen) has been obtained by the mentioned hydrogenation process.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science and Engineering: A - Volumes 521–522, 15 September 2009, Pages 147–150
نویسندگان
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