کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
158119 456996 2007 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modelling NOxNOx adsorption in a thin NaZSM-5 film supported on a cordierite monolith
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Modelling NOxNOx adsorption in a thin NaZSM-5 film supported on a cordierite monolith
چکیده انگلیسی

Transient two dimensional (2-D) and three dimensional (3-D) single channel models (SCMs) describing transport of NOxNOx into a NaZSM-5 film and kinetics for reactions forming nitrate species were developed. The film consisted of a continuous thin layer of inter-grown NaZSM-5 crystals supported on a cordierite monolith support. The 2-D model which included a comprehensive transport model was developed for studying the adsorption kinetics, whereas the more rigorous 3-D model was used to provide a better picture of radial and axial concentration and velocity variations in the monolith channel and the film. The overall adsorption–desorption mechanism, consisting of two competing reaction schemes for nitrate formation, was sufficient to predict the dynamic development of surface nitrate species. The simulation results showed that the adsorption is strongly influenced by transport resistance in the NaZSM-5 film. Also, the effective diffusion of NOxNOx in the NaZSM-5 film is apparently surface nitrate concentration dependent.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 62, Issue 15, August 2007, Pages 3882–3893
نویسندگان
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