کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1590988 | 1515475 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of DPA dendron encapsulated gold clusters with metal-assembling function
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis of DPA dendron encapsulated gold clusters with metal-assembling function Synthesis of DPA dendron encapsulated gold clusters with metal-assembling function](/preview/png/1590988.png)
چکیده انگلیسی
Gold clusters modified with first, second and third generation dendritic polyphenylazomethines (DPA) were synthesized by an exchanged reaction of corresponding DPA dendron thiols. Measurements by high performance perfect sizer (HPPS) and TEM reveal that their diameters increase with a change in the chain length of the modifying molecules from the first to third generation. These gold clusters with DPA dendrons exhibit coordination quantitatively to metal ions such as Fe3+, Sn2+, etc., because of their imine groups; this then resulted in self-aggregation to form a large sphere.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Science and Technology of Advanced Materials - Volume 7, Issue 2, March 2006, Pages 139-144
Journal: Science and Technology of Advanced Materials - Volume 7, Issue 2, March 2006, Pages 139-144
نویسندگان
Yi Men, Masayoshi Higuchi, Kimihisa Yamamoto,