Composition-dependent metal-insulator transition in perovskite CaXPb(1−X) TiO3 (CPT) ceramic

Ceramic compositions of a complex perovskite CaXPb(1−X)TiO3 (CPT) systems with x=0.6, 0.7 and 0.8 were prepared by mechanical mixing of their oxides (CaTiO3 and PbTiO3). The structure of the (CPT) ceramics was characterized by X-ray diffraction (XRD) The ceramics transform gradually from orthorhombic phase (pseudo cubic phase) to cubic phase by increasing pb content percent. The dc resistivity ρ(t) versus temperature (range 300–525 K) for x=0.6, 0.7 and 0.8. The ρ.T/curves reveal that samples exhibit a metallic behaviour at low temperature and undergo a metal-semiconductor transition with increasing temperature at Tp=373 K, 343 K and 333 K, for x=0.6, 0.7 and 0.8, respectively. The nature of conduction mechanism is studied in semiconductor region by studying the current–voltage temperature characteristics. The current–voltage characteristics were interpreted in terms of Poole–Frenkel type of conduction mechanism.

► Ceramic CaX Pb(1−X) TiO3 systems were prepared by mechanical mixing way.
► The structure of the ceramics was characterized by X-ray diffraction.
► The ceramics transform from orthorhombic phase to cubic phase by increasing Pb%.
► The ceramics exhibits a metal-semiconductor transition with increasing temperature.
► I–V characteristics were interpreted by using Poole–Frenkel conduction mechanism.