کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1593819 | 1002717 | 2011 | 5 صفحه PDF | دانلود رایگان |
We introduce a Raman profiling method to track homogenization of GexSe100−x melts in real time, and show that 2 g melts reacted at 950 °C in high vacuum homogenize in 168 h on a scale of 10μm. Homogenization of melts is precursive to self-organization of glasses. In the present glasses, compositional variation of Raman active corner-sharing mode frequency of GeSe4 units, molar volumes, and the enthalpy of relaxation at TgTg, reveal the rigidity (xc(1)=19.5(3)%xc(1)=19.5(3)%) and the stress (xc(2)=26.0(3)%xc(2)=26.0(3)%) transitions to be rather sharp (Δx<0.6%Δx<0.6%). These abrupt elastic phase transitions are in harmony with rigidity theory and have a direct bearing on the physics of glasses.
► A Raman profiling method is introduced.
► It has permitted the synthesis of homogeneous Ge–Se melts/glasses.
► Sharply defined rigidity and stress transitions appear in such Ge–Se glasses.
► The result are in harmony with rigidity theory.
Journal: Solid State Communications - Volume 151, Issue 24, December 2011, Pages 1851–1855