کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1593904 1515648 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of SnO2 coating and thermal annealing on the structure and luminescence properties of CuO nanorods
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
Influence of SnO2 coating and thermal annealing on the structure and luminescence properties of CuO nanorods
چکیده انگلیسی

CuO-core/ SnO2-shell one-dimensional nanostructures have been fabricated by thermal oxidation of a copper foil and then atomic layer deposition of SnO2. The structure and optical properties of the nanostructures have been investigated by using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, photoluminescence (PL) spectroscopy, and energy-dispersive X-ray analysis techniques. The nanostructures are found to have the form of nanorods, with the diameter of the CuO cores being in the range from a few tens to a few hundreds of nanometers, the thickness of the SnO2 shells being ∼15 nm, and with a length of a few tens of micrometers. The CuO cores and the SnO2 shells of the as-synthesized nanorods have crystalline monoclinic CuO and amorphous SnO2 structures, respectively, but the SnO2 shells are found to crystallize to tetragonal SnO2 on thermal annealing. The PL emission intensity of the CuO nanorods has been slightly increased by SnO2 coating. The PL emission of the SnO2-coated CuO nanorods is somewhat increased and the emission peak position is red-shifted from 550 to 580 nm by annealing in a reducing atmosphere. On the other hand, the PL emission is significantly increased and the emission peak position is shifted from 550 nm further to around 595 nm by annealing in an oxidative atmosphere. In addition, the origins of the PL enhancements in the nanorods by coating and annealing are discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Communications - Volume 150, Issues 37–38, October 2010, Pages 1812–1817
نویسندگان
, , , , , ,