کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1594612 | 1515667 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Interplay between Ï-stacking and AFM interaction in the novel triazine based dimeric crystal
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Interplay between Ï-stacking and AFM interaction in the novel triazine based dimeric crystal Interplay between Ï-stacking and AFM interaction in the novel triazine based dimeric crystal](/preview/png/1594612.png)
چکیده انگلیسی
We carried out experimental SQUID and EPR studies together with LSDA + U quantum calculations of the electronic spectra and spin density distribution for dimeric crystals [(L)2Cu2Cl2(H2O)], where L=6-phenyl-3-(2-pyridyl)-5-trifluoroacetylmethylidene-4,5-dihydro-1,2,4-triazine. We found experimentally and confirmed numerically that μeff(T), T<52K, and M(B),T=2K, are affected by intradimer spin polarization of the 1,2,4-triazine fragment and interstack exchange interactions. The interplay between Ï-stacking and Cu1-Cu1# antiferromagnetic coupling causes a structure instability which ends up by spontaneous destruction of the crystal at 2 K under influence of DC and AC magnetic fields.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Communications - Volume 149, Issues 47â48, December 2009, Pages 2189-2193
Journal: Solid State Communications - Volume 149, Issues 47â48, December 2009, Pages 2189-2193
نویسندگان
Yu.N. Shvachko, D.V. Starichenko, A.V. Korolev, D.W. Boukhvalov, V.V. Ustinov,