کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1595165 | 1515670 | 2009 | 4 صفحه PDF | دانلود رایگان |
Electron paramagnetic resonance (EPR) and electron-nuclear double resonance (ENDOR) are used to identify and characterize V 4+ ions in a bulk single crystal of vanadium dioxide (V O2). These S=1/2S=1/2 defects are observed in the as-grown crystal because an adjacent nonmagnetic M4+ impurity, e.g., a Si4+ ion, has destroyed the normal antiferromagnetic coupling associated with the close pairs of V 4+ ions that occur in the low-temperature monoclinic phase of V O2. EPR spectra taken near 5 K with the magnetic field along the [110] and [001] axes show resolved hyperfine patterns due to one 51V nucleus. ENDOR spectra taken at 5 K with the magnetic field parallel to the [001] axis have large nuclear electric quadrupole splittings as a result of a significant electric field gradient at the 51V nucleus. Spin-Hamiltonian parameters describing the electron Zeeman, hyperfine, and nuclear electric quadrupole interactions are reported.
Journal: Solid State Communications - Volume 149, Issues 41–42, November 2009, Pages 1818–1821