Spin dynamics in annealed Mn-doped ZnO ceramic materials

Influence of annealing on the electron spin resonance (ESR) spectra of Zn1−xMnxO:1 mol% Zn3P2 (x=0.01x=0.01 and 0.02) ceramics was systematically investigated. The samples were annealed at temperatures (Tan) between 200 and 1100 ∘C for 12 h. The ESR spectra revealed the three characteristic regions. In the first region (200≤Tan<700∘C), the ESR spectra exhibited a broad Lorentzian-type single line, and the ESR intensity decreased with increasing Tan. In the second region (700≤Tan<1000∘C), the ESR spectra appeared Mn2+ hyperfine lines within a broad Lorentzian single line, indicating that Mn2+ ions substituted into Zn2+ lattice sites. The signal intensity and number of Mn2+ hyperfine lines increased with increasing Tan. In the third region (Tan≥1000∘C), the Mn2+ hyperfine lines became broadened and finally blurred into the background line, resulting in a strong increase in the ESR signal. The origins of the ESR spectra, in relation to their X-ray diffraction patterns, are elucidated.