کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1595995 | 1515703 | 2008 | 4 صفحه PDF | دانلود رایگان |
Monodisperse Zn ferrite nanospheres and its Ba substitution nanosheets were successfully prepared by a facile solvothermal method. The size, morphology, and structure of the as-prepared products were investigated in detail by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and inductively coupled plasma atomic emission spectroscopy (ICP-AES). Magnetic studies revealed that Zn ferrite nanospheres are ferrimagnetic with a saturation magnetization (Ms)(Ms) of 49.6 emu /g and MsMs increased from 49.6 emu /g to 84.2 emu /g when Ba2+ was substituted into Zn ferrite to form BaZn ferrite nanosheets. To explain the variations of morphology and magnetic properties, the strong preferential occupancy of cations in chemically equivalent A and B sites and the metastable cation distribution in nanoparticles are invoked.
Journal: Solid State Communications - Volume 146, Issues 11–12, June 2008, Pages 483–486