کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1596187 | 1002810 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tin(IV) derivatives of 2,6-pyridinedicarboxylate: A 119Sn Mössbauer spectroscopic investigation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of organotin(IV) derivatives of 2,6-pyridinedicarboxylate has been investigated by Mössbauer spectroscopy in order to elucidate aspects concerning bonding and structural features in the solid state. A geometrical pattern of five-fold coordination at the metal centre has been revealed for SnCl3Bu and SnClBu3 derivatives. Trans stereochemistry for the butyl and vinyl groups of SnCl2Bu2 and SnCl2(Vin)2 derivatives has also been identified by this method. The isomer shift for the divinyl derivative is concurrent to a 7-coordinate metal centre contrasting to that for the dibutyl one. Although there is a discrepancy in isomer shift between these compounds, both have seven-fold coordination at the Sn(IV) nucleus. The resulting data has given evidence that 2,6-pyridinedicarboxylate is acting as a tridentate ligand through pyridil and carbolxylate moiety to all derivatives except for SnClBu3. For the latter, the coordination mode occurs via carboxylate groups. The overall data support distorted geometrical pattern to all complexes in solid state.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Communications - Volume 137, Issue 7, February 2006, Pages 376-380
Journal: Solid State Communications - Volume 137, Issue 7, February 2006, Pages 376-380
نویسندگان
Luiz C.M. Costa, José Roberto da S. Maia, Geraldo M. de Lima, José D. Ardisson,