The effect of sintering temperature on the intergranular properties of Bi2223 superconductors

A systematic study of the intergranular properties of (Bi,Pb)2Sr2Ca2Cu3Oy (Bi2223) polycrystalline samples has been done using the electrical resistivity and Ac susceptibility techniques. In this project, we have prepared a series of Bi2223 samples with different sintering temperature. The XRD results show that by increasing sintering temperature up to 865 °C the Bi2212 phase fraction decrease. It was found that the Bi2212 phase on the grain boundaries is likely to play the role of weak links and consequently reduces the intergranular critical current densities. Analysis of the temperature dependence of the Ac susceptibility near the transition temperature (Tc) has been done employing Bean's Critical State Model. The observed variation of intergranular critical current densities (Jc) with temperature indicates that the weak links are changed from superconductor-normal metal-superconductor (SNS) for well-coupled sample to superconductor-insulator-superconductor (SIS) type of junctions for the sample with high Bi2212 phase fraction.