کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1635022 | 1007010 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of layered oxide Li(Co1/3Ni1/3Mn1/3)O2 via the sol-gel process
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
To obtain homogenous layered oxide Li(Co1/3Ni1/3Mn1/3)O2 as a lithium insertion positive electrode material, the sol-gel process using citric acid as a chelating agent was applied. The material Li(Co1/3Ni1/3Mn1/3)O2 was synthesized at different calcination temperatures. XRD experiment indicated that the layered Li(Co1/3Ni1/3Mn1/3)O2 material could be synthesized at a lower temperature of 800°C, and the oxidation state of Co, Ni, and Mn in the cathode confirmed by XPS were +3, +2, and +4, respectively. SEM observations showed that the synthesized material could form homogenous particle morphology with the particle size of about 200 nm. In spite of different calcination temperatures, the charge-discharge curves of all the samples for the initial cycle were similar, and the cathode synthesized at 900°C showed a small irreversible capacity loss of 11.24% and a high discharge capacity of 212.2 mAh·gâ1 in the voltage range of 2.9-4.6 V.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Rare Metals - Volume 27, Issue 2, April 2008, Pages 158-164
Journal: Rare Metals - Volume 27, Issue 2, April 2008, Pages 158-164
نویسندگان
ZHANG Wen, LIU Hanxing, HU Chen, ZHU Xianjun, LI Yanxi,