کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1635811 1516950 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Response surface methodology for optimizing adsorption performance of gel-type weak acid resin for Eu(III)
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Response surface methodology for optimizing adsorption performance of gel-type weak acid resin for Eu(III)
چکیده انگلیسی

The conditions relating to enhanced adsorption procedure of earth element europium (Eu) onto gel-type weak acid resin (110-H) in aqueous solution were optimized by means of the response surface methodology (RSM), which proved that 110-H owned satisfactory adsorption capacity (346.85 mg/g) in optimum conditions, belonging to one of the high adsorption capacity materials. Then, the adsorption and desorption behaviors were investigated by batch studies. The adsorption performance showed high agreement with the Lagergren-first-order model and Langmuir isotherm with thermodynamic adsorption parameters of ΔH= 36.1 kJ/mol and ΔS=200 J/(mol-K). Desorption study revealed that 110-H could be effectively eluted by a low concentration of HCl solution (0.1 mol/L) to regenerate and reuse. Finally, the 110-H and Eu(III) loaded 110-H were characterized by IR spectroscopy and scanning electron microscope (SEM) to analyze the mechanism of adsorption, which proved to be chemisorbed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 25, Issue 12, December 2015, Pages 4207-4215