کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1637503 | 1517002 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, crystal structure and magnetic properties of novel copper compound Cu(phen)(m-CBA)2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, crystal structure and magnetic properties of novel copper compound Cu(phen)(m-CBA)2 Synthesis, crystal structure and magnetic properties of novel copper compound Cu(phen)(m-CBA)2](/preview/png/1637503.png)
چکیده انگلیسی
A novel compound Cu(phen)(m-CBA)2 was synthesized with m-chlorobenzoic acid(m-CBA), 1,10-phenanthroline(phen) and Cu(OAc)2·H2O. It was characterized by IR, UV, elemental analyses and X-ray crystallography. It crystallizes in the monoclinic crystal system with C2/c space group, a=2.9699(4) nm, b=1.15452(2) nm, c=1.5335(2) nm, β=111.118(2)°, V=4.905 1(1) nm3, Z=8, F(000)=2 328, R1=0.072 8, wR2=0.223 4 [I>2Ï(I)]. Structure analysis shows that the copper center coordinates with two nitrogen atoms from one 1,10-phenanthroline molecule, two oxygen atoms from two m-chlorobenzoic acid molecules, giving a distorted squared planar coordination geometry. This novel compound shows paramagnetic interactions between copper centers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 21, Issue 12, December 2011, Pages 2660-2664
Journal: Transactions of Nonferrous Metals Society of China - Volume 21, Issue 12, December 2011, Pages 2660-2664
نویسندگان
Jian-liang ZHOU, Yan HUO, Min-min WANG, Yuan-yuan WANG, Ying-ying GU, Xiao-yi YI, Shou-chun ZHANG,