کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1637517 1517002 2011 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Adsorption of ytterbium (III) from aqueous solution by SQD–85 resin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Adsorption of ytterbium (III) from aqueous solution by SQD–85 resin
چکیده انگلیسی

Adsorption and desorption behavior of Yb (III) by SQD-85 resin was investigated by various chemical methods and IR spectrometry. The adsorption capacity of SQD–85 resin for Yb (III) was studied as a function of solution pH, initial concentration of Yb(III), temperature and contact time. The optimal pH for the adsorption was 5.50 in the HAc-NaAc system, and the maximum adsorption capacity was estimated to be 347.6 mg/g at 308 K. The isotherms adsorption data fit well with Langmuir model. The adsorption kinetics data are in agreement with pseudo-second-order model. Thermodynamic parameters indicate that Yb (III) adsorption by SQD–85 resin is endothermic and spontaneous in nature. Thomas model is reasonably accurate in predicting experimental column results. The dynamic desorption rate of Yb(III) can increase to 97.3% when the elution agent is 1.0 mol/L HCl. These results suggest that Yb(III) in aqueous solution can be removed and recovered by SQD–85 resin efficiently.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 21, Issue 12, December 2011, Pages 2764-2771