کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1637587 1516972 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical behavior and cyclic fading mechanism of LiNi0.5Mn0.5O2 electrode in LiNO3 electrolyte
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Electrochemical behavior and cyclic fading mechanism of LiNi0.5Mn0.5O2 electrode in LiNO3 electrolyte
چکیده انگلیسی
Electrochemical behavior of layered LiNi0.5Mn0.5O2 in LiNO3 aqueous solution and its cyclic fading mechanism in electrolytes with different pH values were investigated. CV results show that LiNi0.5Mn0.5O2 has good electrochemical reversible behaviors in 5 mol/L LiNO3 solution. Meanwhile, the electrode in 5 mol/L LiNO3 with pH value of 12 demonstrates the best electrochemical stability. Based on the electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD) and scanning electron microscopy (SEM) results, it is proposed that suppressed charge-transfer resistance is the major reason, which is probably ascribed to the more stable electrode surface and less structure change.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 24, Issue 2, February 2014, Pages 415-422
نویسندگان
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