کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
167100 1423398 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Gas-phase dehydration of glycerol over commercial Pt/γ-Al2O3 catalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Gas-phase dehydration of glycerol over commercial Pt/γ-Al2O3 catalysts
چکیده انگلیسی

Gas-phase dehydration of glycerol to produce acrolein was investigated over commercial catalysts based on γ-Al2O3, viz. A-64, A-56, I-62, AP-10, AP-56, AP-64 and KR-104. To understand the effect of Cl− anions, HCl-impregnated supports have been investigated in the dehydration reaction of glycerol at 375 °C. For comparison, various H-zeolites were also examined. It was found that the glycerol conversion over the solid acid catalysts was strongly dependent on their acidity and surface area. And the relationship between the catalytic activity and the acidity of the catalysts was discussed. The outstanding properties of Pt/γ-Al2O3 catalyst systems for the dehydration of glycerol were revealed. Pt/γ-Al2O3 catalyst (AP-64) showed the highest catalytic activity after 50 h of reaction with an acrolein selectivity of 65% at a conversion of glycerol of 90%. Based on these results, catalysts based on γ-Al2O3 appear to be most promising for gas phase dehydration of glycerol.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 23, Issue 7, July 2015, Pages 1138–1146
نویسندگان
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