کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
167246 1423402 2015 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Densities and viscosities of binary mixtures of n-decane + 1-pentanol, + 1-hexanol, + 1-heptanol at temperatures from 293.15 to 363.15 K and atmospheric pressure
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Densities and viscosities of binary mixtures of n-decane + 1-pentanol, + 1-hexanol, + 1-heptanol at temperatures from 293.15 to 363.15 K and atmospheric pressure
چکیده انگلیسی

Densities (ρ) and dynamic viscosities (η) for three binary mixtures of n-decane with 1-pentanol, 1-hexanol and 1-heptanol are presented at temperatures from 293.15 to 363.15 K and atmospheric pressure over the entire composition range. The density and viscosity are measured using a vibrating tube densimeter and a cylindrical Couette type rotating viscometer, respectively. Excess molar volumes (VE), viscosity deviations (Δη) and excess Gibbs energy of activation of viscous flow (ΔG⁎E) are calculated from the experimental measurements. Intermolecular and structural interactions are indicated by the sign and magnitude of these properties. Partial molar volumes and infinity dilution molar partial volumes are also calculated for each binary system. These results are correlated using Redlich–Kister type equations.

Graphical AbstractFigure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Chemical Engineering - Volume 23, Issue 3, March 2015, Pages 559–571
نویسندگان
, , , , , ,