کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1740696 | 1521766 | 2014 | 4 صفحه PDF | دانلود رایگان |
• Synthesis of Nd2xZr1−xO2+x ceramics by a coprecipitation route.
• Dissolution kinetics studied at 90 °C in C(HCl) = 0.1 M in batch and dynamic setups.
• Data show a higher stability of Zr-based B-sublattice in the pyrochlore structure.
• Batch and dynamic steady state dissolution rate of pyrochlore in good agreement.
• No significant difference in dissolution rates of defect fluorite and pyrochlore.
In this study, an ideal Nd2Zr2O7 pyrochlore and a defect fluorite ceramic were synthesised by coprecipitation, pressing and sintering. Detailed investigations by electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (XRD) were used for the characterisation of the powders. In particular both powders were found to be single phase ceramics.All batch and dynamic dissolution experiments were conducted in C(HCl) = 0.1 M at 90 °C to compare the two types of Nd-zirconia structures and the experimental approaches. A good agreement between batch and dynamic dissolution experiments was observed for the pyrochlore with a Nd-based final dissolution rate in the range between 0.84 × 10−5 and 1.95 × 10−5 g m−2 d−1. The dynamic experiments indicate a strongly incongruent preferential release of Nd from the pyrochlore ceramic at the beginning of the experiment and a close to congruent dissolution at the end of the experiment.The dissolution behaviour of defect fluorite in dynamic experiments is observed to be very similar to the pyrochlore. An incongruent dissolution during the early stages is followed by a congruent steady state. The defect fluorite steady state dissolution rate is lower than the one determined for pyrochlore.
Journal: Progress in Nuclear Energy - Volume 72, April 2014, Pages 130–133