کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
175370 458909 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Colorimetric polarity chemosensor based on a organometal halide perovskite functional dye
ترجمه فارسی عنوان
قطبش کلریمتری کیموسنزور بر اساس یک فلز پرتوزوئیک متشکل از متالورمون متال هالید
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• Organometal halide perovskite is used as a colorimetric chemosensor.
• Polar species can be detected based on hydrogen bonding interaction with perovskite.
• Color change rate of perovskite by alcohol is proportionally increased with increased polarity of alcohols.

We have investigated polarity sensing of organometal halide CH3NH3PbI3 perovskite functional dye based on hydrogen bonds between alcohols and polar units in perovskite. Upon exposure of alcohol solvents, perovskite film showed a drastic visible color change with different changing time depending on the polarities of alcohols. From the kinetic study of the reaction between perovskite dye and alcohols having different polarities, efficiency of hydrogen-bonding interactions between them were clearly revealed to be the main sensing mechanism, which enables effective discrimination of polarities by naked eyes. This study suggests a novel and practical sensing platform for highly sensitive colorimetric polarity chemosensors.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 133, October 2016, Pages 73–78
نویسندگان
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