کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
175503 458912 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A pillar[5]arene-based cyanide sensor bearing on a novel cyanide-induced self-assemble mechanism
ترجمه فارسی عنوان
سنسور سیانید پایه ای [5] بر روی مکانیسم خودمختاری ناشی از سیانید جدید استوار است
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• A novel copillar[5]arene PQ5 was synthesized for the sensor detection of CN−.
• A novel cyanide-induced self-assemble mechanism was proposed.
• The detection limits of the sensor for CN− were found to be 1.08 × 10−8 mol L−1.
• It's the first example of pillararene based cyanide chemosensors.

We have designed and synthesized a novel copillar[5]arene-based chemosensor, which employ 8-hydroxyquinoline group as a binding site and signal group. By a novel cyanide-induced self-assemble mechanism, the pillar[5]arene-based chemosensor shown high sensitivity and selectivity for cyanide in aqueous media. When cyanide was added to the solution of the chemosensor, a strong chartreuse fluorescence appeared. The detection limit of the fluorescent spectrum is 1.08 × 10−8 mol L−1 for cyanide. Moreover, test strips based on the sensor were fabricated, the chemosensor is a good cyanide test kits. In addition, we made life applications of cyanide detected, the chemosensor is also could detect cyanide in aqueous extracts from sprouting potatoes. It is worth mentioning that cyanide-induced self-assemble mechanism is a novel strategy for the design of pillararene based chemosensor. Moreover, to the best of our knowledge, it's the first example of pillararene based cyanide chemosensors.

A novel copillar[5]arene PQ5 is demonstrated to fluorescently sense CN− in aqueous media based on the mechanism of a novel cyanide-induced self-assemble. This work provides a novel approach for the selective recognition of CN− anions.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 127, April 2016, Pages 59–66
نویسندگان
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