کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
175809 458922 2015 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel D–π–A structured porphyrin dyes containing various diarylamino moieties for dye-sensitized solar cells
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Novel D–π–A structured porphyrin dyes containing various diarylamino moieties for dye-sensitized solar cells
چکیده انگلیسی


• Different diarylamino substituents have different electron donating abilities.
• The porphyrin meso diarylamino substituent has a significant influence on the overall solar energy conversion efficiency.
• Fukui function has been employed to evaluate nucleophilicities and electron-donating abilities of amino nitrogen.

A series of novel zinc porphyrins which are featured with a donor–π–acceptor structure have been synthesized for use in the dye-sensitized solar cells. Various diarylamine moiety, such as diphenylamine, iminodibenzyl or iminostilbene, is introduced at porphyrin meso position as an electron donating group. The cell fabricated with the iminodibenzyl-substituted porphyrin sensitizer yields a short circuit photocurrent density of 9.68 mA/cm2, an open-circuit voltage of 740 mV, and a fill factor of 73.48%, corresponding to an overall conversion efficiency (η) up to 5.26%, which is greater than those obtained by diphenylamine- and iminostilbene-substituted porphyrin-sensitized solar cells (η = 4.05% and 2.62%, respectively). The theoretical studies reveal that the iminodibenzyl donor has the strongest electron donating ability among all three diarylamine substituents employed, which is believed to play a significant role in influencing the photovoltaic properties of these sensitizer-based solar cells.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 115, April 2015, Pages 7–16
نویسندگان
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