کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176089 | 458934 | 2014 | 10 صفحه PDF | دانلود رایگان |
• Four new diarylethenes with both benzofuran and benzene moieties were synthesized.
• The diarylethenes exhibited good photochromism and function as notably photoswitches.
• The substituent effects on their properties were discussed in detail.
Four new photochromic diarylethenes with both benzofuran and benzene moieties were synthesized, and the structures of three diarylethenes were determined by single-crystal X-ray diffraction analysis. The six-membered benzene ring was connected directly to the central perfluorocyclopentene unit as an aryl moiety and available to participate in photoisomerization reaction. All the diarylethenes exhibit favorable photochromism and function as notable fluorescence switches in both hexane and poly(methyl methacrylate) films. The electron-donating substituents effectively enhanced the cyclization quantum yields, while the electron-withdrawing substituents notably shifted the fluorescent emission peaks to a longer wavelength in both solution and poly(methyl methacrylate) films. The result indicated that the different substituents linked at the reactive carbon atom of the benzene moiety had a significant effect on their optical and electrochemical properties.
A new class of unsymmetrical diarylethenes with both benzofuran and benzene moieties was synthesized to investigate the substituent effects linked at the reactive carbon atom of benzene moiety on their optoelectronic properties.Figure optionsDownload as PowerPoint slide
Journal: Dyes and Pigments - Volume 101, February 2014, Pages 15–24