کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
176169 458936 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Divinyl sulfides/sulfones-based D–π–A–π–D dyes as efficient non-aromatic bridges for π-conjugated compounds
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Divinyl sulfides/sulfones-based D–π–A–π–D dyes as efficient non-aromatic bridges for π-conjugated compounds
چکیده انگلیسی


• Novel photoactive divinyl sulfides and sulfones obtained by a Wittig–Horner reaction.
• Photophysics tailored by solvent polarity.
• Photophysical behavior due to intramolecular charge transfer in the excited state.
• Thermal stable, non-heterocyclic nucleus with an efficient ICT mechanism.
• Sulfones behave as a “push–pull-like” architecture.

Novel photoactive divinyl sulfides and sulfones have been obtained by a straightforward approach using a Wittig–Horner reaction. These compounds behave as quadrupolar chromophores and show absorption in the UV region and fluorescence emission tailored by the solvent polarity due to an intramolecular charge transfer mechanism in the excited state, confirmed by the large Stokes' shift and the positive solvatochromism exhibited by their fluorescence spectra. In particular, a large Stokes' shift has been achieved for the sulfone containing the carbazole moiety, which behaves like a “push–pull” architecture. These new molecules represent an efficient alternative as stable non-heterocyclic π-conjugated compounds for potential applications as photoactive or two-photon absorption chromophores.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 102, March 2014, Pages 71–78
نویسندگان
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