کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176254 | 458938 | 2014 | 6 صفحه PDF | دانلود رایگان |
• A synthetic strategy to introduce an acetylacetone (acac) group onto an aryl moiety.
• FT-IR spectroscopy reveals effective binding of the acac group to the NiO surface.
• Ultrafast hole injection (<200 fs) into NiO is compatible with acac anchor.
• acac is a valuable anchoring group for NiO based photoelectrochemical device.
In this article, the viability of the first push–pull (nitrophenyl and hexyl-thiophene as acceptor and donor unit respectively) sensitizer functionalized with acetylacetone (acac) anchoring group was assessed for application in p-type dye sensitized solar cells (NiO-based). An effective synthetic strategy to introduce the acac directly to an aryl moiety was developed. Then, the UV–visible absorption, emission and electrochemical properties of this new sensitizer were determined. FT-IR spectroscopy revealed an effective binding of the acac group to NiO surface while time-dependent density functional theory (TD-DFT) calculations predicted a strong charge-transfer transition with no component of the LUMO centred on the acac. Ultrafast hole injection (<200 fs) from the dye excited state into the valence band (VB) of NiO was experimentally demonstrated by transient absorption spectroscopy studies. It was also shown that excitation of the sensitizer leads to the formation of a twisted intramolecular charge transfer (TICT) state. Finally, the photovoltaic performances of this dye were investigated in NiO based solar cells using the iodide/triiodide electrolyte. We measured promising power conversion efficiencies higher than that of the coumarin C343 benchmark reference albeit with a weaker light harvesting efficiency.
Acetylacetone was used for the first time as anchoring group for NiO based p-DSCs and proved to be a promising alternative to carboxylic acid.Figure optionsDownload as PowerPoint slide
Journal: Dyes and Pigments - Volume 105, June 2014, Pages 174–179