کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
176828 458957 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of a group of new medium responsive non-symmetric viologens. Chromotropism and structural effects
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and characterization of a group of new medium responsive non-symmetric viologens. Chromotropism and structural effects
چکیده انگلیسی

A group of new non-symmetric viologens was synthesized and characterized spectrally using various techniques. These viologens contain active methylene moieties being capable to act as hydrogen bond donors (HBD) and interact in solution with various solvents, the latter acting as hydrogen bond acceptors (HBA). These specific solute-solvent interactions result in intense coloration of the resulting solutions. The chromotropic behavior of these compounds is triggered by basic solvents, and no significant change in color is observed in poorer HBA-solvents, such as several alcohols. The dependence of the color of the solutions on the polarity parameters of solvents (solvatochromism) was investigated. Solvent polarity parameters expressing both dipolarity/polarizability and basicity of solvents have been used. Finally the correlation of the chromotropic behavior of these compounds with their structure is examined, using both experimental data and Hammett equation.

Figure optionsDownload as PowerPoint slideHighlights
► We report the synthesis and characterization of new non-symmetric viologen dyes.
► These viologens present a unique chromotropic behavior triggered by HBA-solvents.
► Solvatochromic species are produced by specific solute-solvent interactions.
► Their medium responsive behavior is quantified and dipole moments are determined.
► The structure–properties relation is studied using 13C-NMR and Vis spectral data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 95, Issue 3, December 2012, Pages 478–484
نویسندگان
, , ,