کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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177018 | 458962 | 2012 | 7 صفحه PDF | دانلود رایگان |

Three novel donor-acceptor polymeric metal complexes based on polycarbazole containing complexes of 1,10-phenanthroline with Zn(II), Cd(II) and Ni(II) have been synthesized by the Ullmann reaction and characterized by gel permeation chromatography, FT-IR, UV–visible absorption and photoluminescence spectroscopy, cyclic voltammetry and elemental analysis. The application of these organometallic polymers in fabricated dye-sensitized solar cells has been studied. The solar cells exhibited good device performance with a power conversion efficiency of up to 0.44%, under simulated air mass 1.5 G solar irradiation.
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► The synthesis of three novel D–A polymeric metal complexes is described.
► The polymeric metal complexes have excellent thermal stability.
► The application of the organometallic polymers in dye-sensitized solar cells was investigated.
► The Cd complex polymer exhibited better device performance than either the Zn or Ni complexes.
Journal: Dyes and Pigments - Volume 92, Issue 3, March 2012, Pages 1062–1068