کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177031 | 458962 | 2012 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, characterization and DFT investigation of aluminum complexes of aryl- substituted-8-hydroxyquinoline Synthesis, characterization and DFT investigation of aluminum complexes of aryl- substituted-8-hydroxyquinoline](/preview/png/177031.png)
New aryl substituted 8-hydroxyquinoline derivatives have been synthesized. The compounds were characterized by 1H, 13C-NMR spectroscopy and mass spectrometry. The aluminum complexes of these derivatives show strong green emission in the range 530–535 nm with high quantum yield compared to the parent tris (8-hydroxyquinolinato)aluminum(III) complex. The structure of the aryl-substituted 8-hydroxyquinoline aluminum complexes in the ground state have been optimized at the B3LYP/6-31G* level of theory. The parent 8-hydroxyquinoline has also been examined using this method with the same basis set. A clear correlation between the shortening of the Al-N bond and red shift in the fluorescence emission band was observed. We have also found that substitution at the 5 and 7 position of the 8-hydroxyquinoline ligand cause simultaneous energy lowering of both highest occupied molecular orbital and the lowest unoccupied molecular orbital with the 5, 7-aryl substituted derivatives exhibiting the greatest effect.
► Synthesis of new 5, 7-aryl 8-hydroquinoline derivatives.
► The new Al complexes dyes exhibit higher quantum yields than the parent compound.
► Energy gaps were calculated by DFT B3LYP methods.
► DFT B3LYP methods show that 5- and 7-substitution stabilizes both HOMO and LUMO.
Journal: Dyes and Pigments - Volume 92, Issue 3, March 2012, Pages 1153–1159