کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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177135 | 458966 | 2011 | 8 صفحه PDF | دانلود رایگان |
The changes in the photophysical properties of two novel, yellow-green emitting pH chemosensors namely a 1,8-naphthalimide dye and its condensed heterocyclic derivative, as a function of pH were investigated in water/ethanol. The 1,8-naphthalimide dye displayed on–off pH sensing properties owing to photoinduced electron transfer, while its condensed heterocyclic derivative revealed off-on-off pH sensor activity derived from simultaneous photoinduced electron transfer and internal charge transfer. In alkaline media the fluorescence of the 1,8-naphthailimide dye was quenched owing to photoinduced electron transfer being disabled in acidic media. The pKa of the 1,8-naphthailimide dye was 5.49, which defines the dye as a highly efficient “off–on” switch. For the heterocyclic 1,8-naphthalimide derivative two fluorescence quenching processes at different pH were observed, one with a pKa value of 6.08 and a second with a pKa value of 3.95. These results indicate that the heterocyclic derivative would be able to act as an efficient “off–on–off” fluorescent pH switch.
Journal: Dyes and Pigments - Volume 88, Issue 3, March 2011, Pages 350–357