کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177256 | 458972 | 2011 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Syntheses and photochromic properties of diaryl acenaphthylene derivatives
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of diaryl acenaphthylenes has been synthesized, and their photochromic properties are studied both in solution and in the crystalline state. 2,4-Dimethyl-5-phenylthiophene derivative 1a showed no photochromic reaction, while 2-methyl-5-phenylthiophene derivative 2a and 5-methyl-2-phenylthiazol derivative 3a showed reversible photochromism in solution. Fluorescence spectrum of compound 3a changed upon photoirradiation. In the single-crystal state, compound 3a showed no photochromic reaction possibly because of π–π and CH/S inter-molecular interactions. The photocyclization quantum yield of 3a was determined to be as low as 0.7%. The closed-isomer 3b showed relatively high thermal stability by the rigidity of acenaphtylene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 89, Issue 3, June 2011, Pages 297–304
Journal: Dyes and Pigments - Volume 89, Issue 3, June 2011, Pages 297–304
نویسندگان
Sayo Fukumoto, Tetsuya Nakagawa, Shigekazu Kawai, Takuya Nakashima, Tsuyoshi Kawai,