کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177380 | 458980 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Colorimetric sensing of Cu2+ using a cyclodextrin–dye rotaxane
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A dye rotaxane having 8-hydroxyquinoline as coupling component was prepared in the presence of α-cyclodextrin and its structure identified using NMR. The dye rotaxane displayed high color strength regardless of the solvent used and responded to changes in pH based on tautomeric equilibrium, without any interference by the cyclodextrin macrocycle. Compared to the non-rotaxanated forms, the dye rotaxane displayed a characteristic spectral response to the presence of Cu2+ which was attributed to the formation of a polymeric, metal–dye rotaxane complex which was of high solubility because of the presence of cyclodextrin. Thus, this approach can clearly be used as a facile and efficient sensor for copper ions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 87, Issue 1, September 2010, Pages 49–54
Journal: Dyes and Pigments - Volume 87, Issue 1, September 2010, Pages 49–54
نویسندگان
Jong S. Park, Sooyeon Jeong, Seongkook Dho, Myungwon Lee, Chungkun Song,