کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177423 | 458983 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A rhodamine-based dual chemosensor for the visual detection of copper and the ratiometric fluorescent detection of vanadium
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The optical properties of a novel, rhodamine-based derivative, synthesized by reacting rhodamine hydrazide and 5-chlorosalicylaldehyde in ethanol, were investigated in methanol:HEPES solution. The novel sensor displayed selectivity for Cu2+, as evidenced by a colourless to dark red colour change, which was characterized using UV–visible spectroscopy and which also allowed visual detection of Cu2+. In contrast, selectivity towards VO2+ was determined from changes in the emission spectra in the nanomolar range. This represents the first reported rhodamine-based sensor capable of detecting both Cu2+ and VO2+ using two different modes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 86, Issue 1, June 2010, Pages 50–55
Journal: Dyes and Pigments - Volume 86, Issue 1, June 2010, Pages 50–55
نویسندگان
Fang-Jun Huo, Jing Su, Yuan-Qiang Sun, Cai-Xia Yin, Hong-Bo Tong, Zong-Xiu Nie,