کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
177813 459002 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The synthesis and properties of novel, functional azobenzene based metal complexes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The synthesis and properties of novel, functional azobenzene based metal complexes
چکیده انگلیسی

Azobenzene-containing metal complexes with different carbon chain lengths connecting the azobenzene moiety and the diamine ZnCl2 unit were characterized using spectrophotometric methods as well as thermal and X-ray diffractometric analysis. The length of the chain between the azobenzene moiety and the diamine metal complex influences both the thermal and fluorescent behaviour of the bi-functional compounds. Combining the azobenzene chromophore with the metal complex results in remarkably high azobenzene isomerization as well as two-band fluorescence emission centered at 290 and 560 nm respectively, imparted by the metal complex component. A holographic image inscription and readout experiment of one of the metal complexes in a poly(methyl methacrylate) matrix is described.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 83, Issue 3, December 2009, Pages 291–296
نویسندگان
, , ,