کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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177813 | 459002 | 2009 | 6 صفحه PDF | دانلود رایگان |

Azobenzene-containing metal complexes with different carbon chain lengths connecting the azobenzene moiety and the diamine ZnCl2 unit were characterized using spectrophotometric methods as well as thermal and X-ray diffractometric analysis. The length of the chain between the azobenzene moiety and the diamine metal complex influences both the thermal and fluorescent behaviour of the bi-functional compounds. Combining the azobenzene chromophore with the metal complex results in remarkably high azobenzene isomerization as well as two-band fluorescence emission centered at 290 and 560 nm respectively, imparted by the metal complex component. A holographic image inscription and readout experiment of one of the metal complexes in a poly(methyl methacrylate) matrix is described.
Journal: Dyes and Pigments - Volume 83, Issue 3, December 2009, Pages 291–296