کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
178233 | 459029 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of new metal-free and phthalocyanine nickel(II) complex containing macrocyclic moieties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and characterization of new metal-free and phthalocyanine nickel(II) complex containing macrocyclic moieties Synthesis and characterization of new metal-free and phthalocyanine nickel(II) complex containing macrocyclic moieties](/preview/png/178233.png)
چکیده انگلیسی
A new metal-free and metallophthalocyanine carrying four 1,1′-biphenyl crown ether units on peripheral positions have been synthesized. Metal-free phthalocyanine was prepared by the reaction of 2,3-(4′,5′-dicyanobenzo)-11,12:13,14-di(1′,2′-biphenyl)-1,4,7,10,15,18-hexaoxacycloeicosa-2,11,13-triene with dry 2-(N,N-dimethylamino)ethanol under reflux. Metal derivative of phthalocyanine was also synthesized by the anhydrous NiCl2 and metal-free phthalocyanine in dry quinoline under reflux. The target symmetrical phthalocyanines were separated by column chromatography and characterized by elemental analysis, 1H, 13C NMR, IR, UV–visible and FAB mass spectroscopies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 74, Issue 1, 2007, Pages 21–25
Journal: Dyes and Pigments - Volume 74, Issue 1, 2007, Pages 21–25
نویسندگان
Halit Kantekin, Murat Rakap, Yaşar Gök, Halil Zeki Şahinbaş,