Phase transitions and dielectric properties of (1 − x)KNbO3 − xK0.5Bi0.5TiO3 ceramics synthesized by a stirred hydrothermal process

• New solid solutions (1 − x) KNbO3 − xK0.5B0.5TiO3 synthesized by a hydrothermal process.
• High quality of ceramics (93–98%) sintered at lower temperature.
• Phase transition and MPB solid solution followed by DRX and Raman.
• Good dielectric properties and AC conductivity remains constant for all ceramics.
• Dielectric relaxation shows at low temperature below 150 K.

Dielectric ceramic materials (1 − x) KNbO3 − xK0.5Bi0.5TiO3 (0 ≤ x ≤ 0.3) have been successfully synthesized via a stirred (dynamic) hydrothermal method. The microstructure, relative density and dielectric properties were studied as a function of KBT doping. The structure of the solid solutions changed from orthorhombic (x = 0; 0.05) to tetragonal (x = 0.1; x = 0.3) at room temperature. The morphotropic phase limit was obtained at x = 0.075 where we have noted the coexistence of the orthorhombic and tetragonal structures. The mean value of the measured dielectric permittivity εr was 700 and dielectric loss tanδ was about 0.06 at room temperature. The dielectric properties of the studied ceramics, from 80 to 450 K, depend not only on their microstructure but also on their relative density. A relaxation behavior was observed for the tanδ curves at temperature below 150 K. The activation energy (Ea) of this phenomenon increases from 0.15 to 0.34 eV with the increase of KBT amount. The conductivity σac remains constant at about 10−6 S m−1.