کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1785456 | 1023381 | 2016 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Investigation on the local electronic/atomic structure properties using XANES/EXAFS and photocatalyst application of Zr1−xCuxO2 (0 ≤ x ≤ 0.2) Investigation on the local electronic/atomic structure properties using XANES/EXAFS and photocatalyst application of Zr1−xCuxO2 (0 ≤ x ≤ 0.2)](/preview/png/1785456.png)
• Zr1−xCuxO2 (0 ≤ x ≤ 0.2) Photocatalysts were synthesized using co-precipitation method.
• XRD, HR-TEM, XANES, EXAFS and photocatalysis measurements were performed.
• Zr+4 ions with local monoclinic structure were dominantly present.
• UV light driven degradation of methyl-orange is achieved.
We investigated local electronic/atomic structure properties by using X-ray absorption spectroscopy and demonstrated the photocatalyst application of Zr1−xCuxO2 (0 ≤ x ≤ 0.2) samples. X ray diffraction (XRD) results revealed the amorphous nature of the samples; however, transmission electron microscopy (TEM) depicted the formation of <2 nm sized particles in all of the samples. Local electronic structure was investigated by X-ray absorption near edge structure (XANES) at O K-edge, Zr K-edge and Cu K-edge. The O K-edge XANES suggested strong hybridization of s-p-d orbitals upon Cu doping. The Cu K-edge XANES confirmed +1 valence state of Cu (Cu+1) in all of the Cu doped ZrO2samples. Extended X-ray absorption fine structure (EXAFS) analysis at the Zr K-edge nullifies the formation of trivial phases and confirms the local monoclinic structure in all of the samples. Photocatalyst properties of the samples were investigated by monitoring the net degradation in the methyl orange dye aqueous solution under the UV light irradiation. The Cu doped ZrO2 samples exhibited superior photo-catalyst properties over the undoped ZrO2.
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Journal: Current Applied Physics - Volume 16, Issue 10, October 2016, Pages 1326–1333